Studies in organic mass spectrometry. XVIII—The effect of branching in the sidechain upon the fragmentation of 4,6‐dialkyl‐1,3‐dioxanes | Zendy

Monstrey J. | Zendy; van de Sande C. | Zendy; Vandewalle M. | Zendy

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Studies in organic mass spectrometry. XVIII—The effect of branching in the sidechain upon the fragmentation of 4,6‐dialkyl‐1,3‐dioxanes

Author(s) -

Monstrey J.,

van de Sande C.,

Vandewalle M.

Publication year - 1974

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210090715

Subject(s) - fragmentation (computing) , branching (polymer chemistry) , chemistry , hydrogen atom , alkyl , mass spectrum , mass spectrometry , hydrogen , stereochemistry , medicinal chemistry , organic chemistry , chromatography , biology , ecology

The presence of a 2′‐tertiary hydrogen atom has a profound influence on the general fragmentation pattern of 4,6‐dialkyl‐1,3‐dioxanes. Branching at the 2′‐position induces a double hydrogen transfer reaction which is absent in the spectra of 4,6‐ n ‐alkyl‐1,3‐dioxanes.

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