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Mass spectrometry of onium compounds. XXIII—ionisation potentials in the structural assignment of [M – N 2 ] ions from diazo‐oxides
Author(s) -
Thorstad Olav,
Undheim Kjell,
Hvistendahl Georg
Publication year - 1974
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210090512
Subject(s) - diazo , pyrolytic carbon , ion , mass spectrometry , chemistry , oxide , ionization , analytical chemistry (journal) , onium , inorganic chemistry , pyrolysis , organic chemistry , chromatography
The ionisation potential shows that fulven‐6one is formed pyrolytically from o‐benzo‐diazo‐oxide. Appearance potential measurements show increasing pyrolytic contribution to the [M – N 2 ] species with increase in ion source temperature.
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