Elimination reactions of ions in the gas phase–I: Elimination of water and acetic acid in epimeric borneols and bornylacetates | Zendy

Robbiani R. | Zendy; Seibl J. | Zendy

Premium

Elimination reactions of ions in the gas phase–I: Elimination of water and acetic acid in epimeric borneols and bornylacetates

Author(s) -

Robbiani R.,

Seibl J.

Publication year - 1973

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210071004

Subject(s) - acetic acid , chemistry , ion , labelling , gas phase , elimination reaction , phase (matter) , organic chemistry , medicinal chemistry , biochemistry

Loss of water and acetic acid in the epimeric bornyl alcohols and acetates are shown to be analogous processes by specific 2 H‐labelling. Among several competing mechanisms cis ‐1,2‐elimination is the most important. Mctastable ion characteristics of this specific process exhibit some unusual features and its product is shown to have a different structure from that produced by the competing reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research