Premium
Scrambling in ethane molecular ion: An INDO model for hydrogen exchange before mass spectral fragmentation
Author(s) -
Parker Carol E.,
Bursey Maurice M.,
Pedersen Lee G.
Publication year - 1973
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210070908
Subject(s) - scrambling , diborane , fragmentation (computing) , chemistry , ion , mass spectrum , hydrogen , molecule , hydrogen molecule , organic chemistry , boron , philosophy , linguistics , computer science , operating system
INDO calculations for previously proposed activated complexes for scrambling in ethane molecular ion suggest that the structure equivalent to diborane is more stable than one in which hydrogens on the same side of the molecule exchange positions.