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Gas phase studies of N‐nitrosamines by ion cyclotron resonance spectroscopy
Author(s) -
Billets Stephen,
Jaffe H. H.,
Kaplan Fred
Publication year - 1973
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210070407
Subject(s) - fragmentation (computing) , ion cyclotron resonance , chemistry , ion , mass spectrometry , fourier transform ion cyclotron resonance , polyatomic ion , deuterium , molecule , gas phase , analytical chemistry (journal) , proton , spectroscopy , cyclotron , atomic physics , organic chemistry , chromatography , nuclear physics , computer science , quantum mechanics , physics , operating system
The gas phase basicities of a series of cyclic and acyclic N‐nitrosamines were determined by ion cyclotron resonance techniques. The fragmentation pattern and ion‐molecule reactions of these compounds are discussed in terms of high resolution mass spectrometry and deuterium labeling. The presence of a unique rearrangement of the molecular ion is discussed in terms of specific ion‐molecule proton transfer reactions and fragment ion products.