Transfer processes of alkoxyl groups in iron carbonyl complexes | Zendy

Gambino O. | Zendy; Vaglio G. A. | Zendy; Cetini G. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Transfer processes of alkoxyl groups in iron carbonyl complexes

Author(s) -

Gambino O.,

Vaglio G. A.,

Cetini G.

Publication year - 1972

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210061204

Subject(s) - fragmentation (computing) , deuterium , chemistry , alkoxy group , hydrogen , metastability , mass spectrum , medicinal chemistry , organic chemistry , physics , ion , nuclear physics , alkyl , computer science , operating system

The mass spectra of Fe 2 (CO) 6 C 4 (COOCH 3 ) 4 and Fe 2 (CO) 6 C 4 (COOC 2 H 5 ) 4 are reported. Transfer processes of alkoxyl groups and hydrogen rearrangements are observed, and confirmed by deuterium labelling and the observation of metastable transitions. Fe 3 (CO) 8 C 4 (COOCH 3 ) 4 and Fe 3 (CO) 8 C 4 (COOC 2 H 5 ) 4 give similar breakdown patterns. Likely fragmentation schemes are suggested.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research