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Oxygen migration in primary nitroalkenes under electron‐impact
Author(s) -
Carney Robert L.
Publication year - 1972
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210061109
Subject(s) - fragmentation (computing) , oxygen , chemistry , electron ionization , primary (astronomy) , epoxide , cleavage (geology) , ion , photochemistry , carbon fibers , ionization , electron , bond cleavage , oxygen atom , organic chemistry , molecule , materials science , catalysis , physics , composite material , quantum mechanics , astronomy , fracture (geology) , composite number , computer science , operating system
Several primary nitroalkenes have been shown to undergo migration of oxygen to the carbon‐carbon double bond during mass spectrometric fragmentation. The oxocarbonium ion species which result are rationalized as arising through cleavage of ionized epoxide intermediates.