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Factors influencing the formation of some characteristic fragment ions in the mass spectra of 16‐trimethylsilyloxy androstanes
Author(s) -
Vouros Paul,
Harvey D. J.
Publication year - 1972
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210060904
Subject(s) - mass spectrum , chemistry , ion , fragment (logic) , trimethylsilyl , deuterium , spectral line , stereochemistry , medicinal chemistry , computational chemistry , organic chemistry , mathematics , physics , algorithm , astronomy , quantum mechanics
The mass spectra of the trimethylsilyl derivatives of several steroids containing a 16‐hydroxy function are presented. The mechanisms giving rise to various characteristic fragment ions were investigated with the aid of deuterium and 18 O‐labeling.