Charge Localization: Doubly‐Charged Ion Reactions in Toluene | Zendy

Ast T. | Zendy; Bey J. H. | Zendy; Cooks R. G. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Charge Localization: Doubly‐Charged Ion Reactions in Toluene

Author(s) -

Ast T.,

Bey J. H.,

Cooks R. G.

Publication year - 1972

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210060706

Subject(s) - toluene , ion , metastability , chemistry , kinetic energy , charge (physics) , hydrogen , analytical chemistry (journal) , physics , organic chemistry , quantum mechanics

The kinetic energy released in the major charge‐separation reactions of [C 7 H 8 ] ++ [C 7 H 7 ] ++ and [C 7 H 6 ] ++ formed from toluene, and in the corresponding reactions of toluene‐α‐ d 3 , toluene‐ d 8 and 2,3,4,5,6‐toluene‐ d 6 has been measured. Some fragmenting [C 7 ] ++ ions are linear; in certain cases they have cyclic structures while in others ‘coiling’ of a linear ion to allow hydrogen transfer in the transition state is suggested. From relative metastable ion abundance data it is apparent that nearly complete H/D randomization accompanies these slow reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research