z-logo
Premium
The mass spectra of carboxylic acids—V: Carboxyl‐carboxyl interaction in the fragmentation of some cycloalkene‐1,2‐dicarboxylic acids
Author(s) -
Benoit F.,
Holmes J. L.
Publication year - 1972
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210060511
Subject(s) - cyclopentene , cyclohexene , chemistry , mass spectrum , fragmentation (computing) , cyclohexane , dicarboxylic acid , cycloalkene , cyclobutene , stereochemistry , medicinal chemistry , ion , organic chemistry , hydrocarbon , ring (chemistry) , catalysis , computer science , operating system
The fragmentation mechanisms of the six isomeric cyclohexene‐1,2‐dicarboxylic acids are discussed. Only the 1‐cyclohexene acid, by virtue of the major sequential losses of H 2 O and CO 2 from the molecular ion, is readily distinguishable from its isomers, all of whose mass spectra are closely similar. In contrast to cis and trans cyclohexane‐1,2‐dicarboxylic acids, whose mass spectra were markedly different, the cis and trans cyclohexene‐1,2‐dicarboxylic acids fragment in a similar fashion. The mass spectra of 1‐cyclopentene‐1,2‐dicarboxylic acid and 1‐cyclobutene‐1,2‐dicarboxylic acid also exhibit a strong carboxyl‐carboxyl interaction; the fragmentation behaviour of the 1‐cyclopenteneacid is, however, more complex than that of the 1‐cyclohexene and 1‐cyclobutene acids.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here