Premium
Anchimeric assistance in electron‐impact reactions: Homoallylic systems
Author(s) -
Tomer Kenneth B.,
Turk Jonathan,
Shapiro Robert H.
Publication year - 1972
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210060302
Subject(s) - kinetic energy , allylic rearrangement , series (stratigraphy) , chemistry , electron , computational chemistry , computer science , physics , catalysis , organic chemistry , nuclear physics , quantum mechanics , geology , paleontology
Abstract A combination of a kinetic approach, thermochemical approach and atomic labeling techniques has been employed to demonstrate that several series of allylic and homoallylic bromides undergo Br· expulsion with the aid of remote π‐electron density.