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High‐resolution mass spectra of anti‐ and syn‐isomers of acylferrocene oximes
Author(s) -
Yamakawa Koji,
Hisatome Masao
Publication year - 1972
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210060206
Subject(s) - fragmentation (computing) , oxime , mass spectrum , spectral line , high resolution , chemistry , resolution (logic) , analytical chemistry (journal) , low resolution , mass spectrometry , medicinal chemistry , physics , organic chemistry , chromatography , remote sensing , astronomy , artificial intelligence , computer science , geology , operating system
High‐resolution mass spectra of anti‐ and syn‐acylferrocene oximes were examined at various ionizing voltages and fragmentation patterns of the oximes are presented. Significant differences between the anti‐ and syn‐isomers were found in the fragmentation behaviour of the low voltage (15 to 20 eV) spectrum of formylferrocene oxime.