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Metal‐metal chelate exchange reactions in the ion source of a mass spectrometer
Author(s) -
Terlouw J. K.,
De Ridder J. J.
Publication year - 1971
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210050915
Subject(s) - nickel , chelation , metal , mass spectrometry , mass spectrum , chemistry , ion , metal ions in aqueous solution , transition metal , ligand (biochemistry) , inorganic chemistry , analytical chemistry (journal) , catalysis , environmental chemistry , organic chemistry , chromatography , biochemistry , receptor
Abstract In the mass spectra of several transition metal chelates with diethyldithiocarbamate as a ligand, intense peaks are present which could be assigned to extraneous metal (particularly nickel) containing ions. Using an Au‐Rh coated ion source, evidence was obtained for the occurrence of exchange reactions in the region of the filament assembly.