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Rearrangement in the mass spectrometer via a 3,3,1‐bicyclic reaction path
Author(s) -
Breuer S. W.,
Gladstone W. A. F.,
Hirst P. A.
Publication year - 1971
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210050615
Subject(s) - bicyclic molecule , fragmentation (computing) , deuterium , labelling , chemistry , rearrangement reaction , mass spectrometry , stereochemistry , physics , nuclear physics , organic chemistry , chromatography , computer science , catalysis , biochemistry , operating system
The fragmentation of some azoacylals showed a 3,3,1 bicyclic rearrangement which could be demonstrated by a deuterium labelling study.