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Vapor phase bimolecular reactions of alkyl siliconium and other metal ions in mass spectrometry
Author(s) -
Harvey D. J.,
Horning M. G.,
Vouros Paul
Publication year - 1971
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210050510
Subject(s) - alkyl , carbonium ion , chemistry , ion , mass spectrometry , tin , molecule , alkoxy group , metal ions in aqueous solution , metal , inorganic chemistry , silicon , germanium , vapor phase , photochemistry , organic chemistry , chromatography , physics , thermodynamics
The vapor phase reactions of various metal alkyl and alkoxy ions are discussed. Ions produced from suitable precursors can react with neutral molecules which contain an electronegative site. It appears that ions containing a positively charged silicon, tin, germanium or mercury center are more reactive than corresponding carbonium ions.