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Fluorinated carbohydrates—IX The mass spectra of deoxyfluorohexopyranose derivatives
Author(s) -
Chizhov O. S.,
Kadentsev V. I.,
Zolotarev B. M.,
Foster A. B.,
Jarman M.,
Westwood J. H.
Publication year - 1971
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210050409
Subject(s) - substituent , fluorine , fragmentation (computing) , chemistry , mass spectrum , cleavage (geology) , spectral line , carbon fibers , bond cleavage , mass spectrometry , stereochemistry , computational chemistry , medicinal chemistry , crystallography , organic chemistry , catalysis , materials science , chromatography , physics , astronomy , fracture (geology) , composite number , computer science , composite material , operating system
The mass spectra of some deoxyfluorohexopyranose acetates bearing the fluorine substituent at positions 2,3,4, or 6 were determind. The fragmentation pathways were analogous with those for hexopyranose acetates, except that the cleavage of bonds between carbon atoms was hindered by the attachment of a fluorine substituent to one of the carbon atoms.