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The mass spectra of eleven derivatives of cyanocyclopropane
Author(s) -
Lageot C.
Publication year - 1971
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210050202
Subject(s) - mass spectrum , cyclopropane , substituent , ring (chemistry) , spectral line , chemistry , electron ionization , computational chemistry , stereochemistry , medicinal chemistry , mass spectrometry , organic chemistry , physics , ion , quantum mechanics , chromatography , ionization
Abstract Studies of the mass spectrum of 1,2‐diphenyl 1‐cyclopropane show that a large number of fragmentations and rearrangements take place during the electron‐impact of this compound. The mechanisms involved were identical to those found in the studies previously made on the cyclopropanes. Other patterns of fragmentations and rearrangements will also be shown, resulting from the presence of the cyano and substituted diphenyl groups linked on the propanic ring. The nature of the para substituent is fundamental to the aspect of the mass spectra.