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Mass spectra of some geometric isomers at 1216 Å and 584 Å: The photoionization of isomeric tricyclo [3.2.1.0 2,4 ] octanes and related compounds
Author(s) -
Brion C. E.,
Farmer J. S. Haywood,
Pincock R. E.,
Stewart W. B.
Publication year - 1970
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210040159
Subject(s) - photoionization , chemistry , steric effects , mass spectrum , ionization , electron ionization , spectral line , mass spectrometry , computational chemistry , stereochemistry , organic chemistry , ion , physics , chromatography , astronomy
The photoionization of a series of tricyclic geometric isomers has been studied at 1216 Å and 584 Å in a high resolution mass spectrometer. The fragmentations are discussed in terms of the molecular geometry and non‐bonded steric interactions. Ionization potentials of all isomers are determined by electron‐impact.