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Mass spectrometric studies—VIII. Double hydrogen migration in 1,1‐dimethyl‐2,2‐dibenzoyl hydrazine
Author(s) -
Porter Q. N.,
Seif Mrs Amal E.
Publication year - 1970
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210040138
Subject(s) - chemistry , fission , hydrazine (antidepressant) , mass spectrum , hydrogen , ion , hydrogen bond , mass spectrometry , medicinal chemistry , organic chemistry , molecule , physics , nuclear physics , chromatography , neutron
The m/e 226 peak in the mass spectrum of 1,1‐dimethyl‐2,2‐dibenzoylhydrazine is formed by loss of C 2 H 4 N from the molecular ion, a process involving concerted transfer of two hydrogen atoms from the same methyl group as an accompaniment to NN bond fission.