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The mass spectra of hydroxyquinolizidines
Author(s) -
Hussain M.,
Robertson J. S.,
Watson T. R.
Publication year - 1970
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210040112
Subject(s) - fragmentation (computing) , mass spectrum , deuterium , labelling , chemistry , spectral line , mass spectrometry , mass , computational chemistry , analytical chemistry (journal) , organic chemistry , chromatography , physics , atomic physics , computer science , biochemistry , astronomy , operating system
Abstract The mass spectra of 1‐, 2‐ and 3‐hydroxyquinolizidine have been determined. In all cases the elimination of an hydroxyl radical is a more favoured process than the elimination of water. This has been substantiated by specific deuterium labelling. The fragmentation patterns of the three isomers allow for each compound to be identified specifically.