Loss of carbon dioxide in the mass spectra of some partially fluorinated β‐diketonato iron chelates | Zendy

Clobes A. L. | Zendy; Morris M. L. | Zendy; Koob R. D. | Zendy

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Loss of carbon dioxide in the mass spectra of some partially fluorinated β‐diketonato iron chelates

Author(s) -

Clobes A. L.,

Morris M. L.,

Koob R. D.

Publication year - 1970

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210031005

Subject(s) - tris , carbon dioxide , chemistry , decomposition , chelation , carbon fibers , inorganic chemistry , medicinal chemistry , organic chemistry , materials science , composite number , composite material , biochemistry

Evidence suggesting elimination of carbon dioxide as a decomposition path for tris(1‐phenyl‐4,4,4‐trifluoro‐1,3‐butandionato) iron (III) [Fe(btac) 3 ] and tris (1‐thienyl‐4,4,4‐trifluoro‐1,3, butandionato) iron (III) [Fe(ttac) 3 ] is presented and discussed. A mechanism is proposed for this reaction. Other examples of CO 2 elimination are observed for substituted phenyl Fe(btac) 3 , tris(1‐cyclopropyl‐4,4,4‐trifluoro‐1,3‐butandionato) iron (III) and Co(III) (btac) 3 .

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