Premium
Charge localization in the retro‐Diels‐Alder fragmentation of tetralins
Author(s) -
Lightner D. A.,
Steinberg Frank S.
Publication year - 1970
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210030816
Subject(s) - fragmentation (computing) , tetralin , chemistry , polar effect , alder , electron , diels–alder reaction , photochemistry , medicinal chemistry , organic chemistry , solvent , physics , catalysis , ecology , quantum mechanics , computer science , biology , operating system
The electron‐impact induced retro‐Diels‐Alder reaction of 5‐ and 6‐substituted tetralins has been examined. Most electron‐donating groups at C‐5 retard the fragmentation relative to tetralin; whereas, electron‐withdrawing groups slightly increase the fragmentation.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom