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Mass spectra of the substituted quinuclidines
Author(s) -
Kostyanovsky R. G.,
Mikhlina E. E.,
Levkoeva E. I.,
Yakhontov L. N.
Publication year - 1970
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210030805
Subject(s) - quinuclidine , mass spectrum , fragmentation (computing) , bicyclic molecule , amine gas treating , chemistry , polyatomic ion , ion , stereochemistry , computational chemistry , organic chemistry , computer science , operating system
The mass spectra of the quinuclidine‐2 (and ‐3)‐ones and other functional derivatives of quinuclidine as well as 2‐azaquinuclidine and benzoquinuclidine have been investigated. The fragmentation through the open form of the molecular ion and the applicability of Bredt's rule to amine fragmentation of the bridgehead nitrogen bicyclic systems are discussed.