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Trimethylphosphine and trimethylamine: Rearrangements common to their mass spectra
Author(s) -
Gillis R. G.,
Long G. J.
Publication year - 1969
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210021212
Subject(s) - trimethylamine , metastability , trimethylphosphine , ion , mass spectrum , chemistry , polyatomic ion , carbon fibers , crystallography , materials science , organic chemistry , crystal structure , composite number , composite material
Metastable ions confirm the rearrangement of the [M H] + ion from trimethylphosphine and trimethylamine to give [C 3 H 5 ] + . Two‐carbon fragments are seen but their origin is indeterminate. Extensive loss of H 2 occurs, confirmed by metastable ions, but not of CH 2 .
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