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Electron‐impact induced oxygen migration in the mass spectra of β‐ketoalkylidenephosphoranes
Author(s) -
Aplin R. T.,
Hands A. R.,
Mercer A. J. H.
Publication year - 1969
Publication title -
organic mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.475
H-Index - 121
eISSN - 1096-9888
pISSN - 0030-493X
DOI - 10.1002/oms.1210021010
Subject(s) - mass spectrum , electron ionization , oxygen , spectral line , electron , mass spectrometry , chemistry , decomposition , thermal decomposition , analytical chemistry (journal) , materials science , physics , ion , environmental chemistry , ionization , nuclear physics , organic chemistry , chromatography , astronomy
The mass spectra of six β‐ketoalkylidenephosphoranes have been examined. The spectra all exhibit an electron‐impact induced migration of oxygen to phosphorus reminiscent of their thermal decomposition.