Electron‐impact studies of organometallic molecules—VII.  Some transition metal complexes derived from 3,3,3‐trifluoroprop‐1‐yne | Zendy

Bruce M. I. | Zendy

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Electron‐impact studies of organometallic molecules—VII. Some transition metal complexes derived from 3,3,3‐trifluoroprop‐1‐yne

Author(s) -

Bruce M. I.

Publication year - 1968

Publication title -

organic mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 121

eISSN - 1096-9888

pISSN - 0030-493X

DOI - 10.1002/oms.1210010509

Subject(s) - chemistry , transition metal , group 2 organometallic chemistry , ligand (biochemistry) , molecule , fluorine , metal , fluorocarbon , electron transfer , organometallic chemistry , atom (system on chip) , crystallography , inorganic chemistry , medicinal chemistry , computational chemistry , organic chemistry , catalysis , crystal structure , biochemistry , receptor , computer science , embedded system

The mass spectra of ten complexes derived from 3,3,3‐trifluoroprop‐1‐yne, namely (CF 3 CCH)CO 2 (CO) 6 , (CF 3 CCH) [πC 5 H 5 Ni] 2 , (CF 3 CCH) 3 Co 2 (CO) 4 , CF 3 CH 2 C[Co(CO) 3 ] 3 ,are discussed in terms of their structures. The major processes observed can be satisfactorily explained in terms of (i) loss of carbonyl groups, if present; (ii) loss of one fluorine atom from the parention (iii) elimination of neutral metal fluorides, with ligand transfer reactions in the case of the iron complexes; (iv) elimination of neutral fluorocarbon molecules.

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