Oxygen‐17 nuclear magnetic resonance study of some oxirane derivatives | Zendy

Sauleau A. | Zendy; Sauleau J. | Zendy; Monti J. P. | Zendy; Faure R. | Zendy

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Oxygen‐17 nuclear magnetic resonance study of some oxirane derivatives

Author(s) -

Sauleau A.,

Sauleau J.,

Monti J. P.,

Faure R.

Publication year - 1983

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/omr.1270210614

Subject(s) - steric effects , oxygen , chemistry , additive function , chemical shift , resonance (particle physics) , computational chemistry , nuclear magnetic resonance , organic chemistry , atomic physics , physics , mathematics , mathematical analysis

The 17 O chemical shifts of seventeen variously substituted oxiranes have been measured in CDCI 3 solution. Deviations of δ o from additivity have been interpreted in terms of steric effects and loss of conjugation. Moreover, in the case of certain cis ‐ and trans ‐dimethyl‐substituted compounds, 17 O NMR allows a differentiation between the different molecular configurations.

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