Premium
A 3D finite element approach for the coupled numerical simulation of electrochemical systems and fluid flow
Author(s) -
Bauer Georg,
Gravemeier Volker,
Wall Wolfgang A.
Publication year - 2011
Publication title -
international journal for numerical methods in engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.421
H-Index - 168
eISSN - 1097-0207
pISSN - 0029-5981
DOI - 10.1002/nme.3107
Subject(s) - finite element method , boundary value problem , partial differential equation , mechanics , algebraic equation , method of fundamental solutions , flow (mathematics) , mathematics , mathematical analysis , physics , boundary element method , boundary knot method , thermodynamics , nonlinear system , quantum mechanics
A comprehensive finite element method for three‐dimensional simulations of stationary and transient electrochemical systems including all multi‐ion transport mechanisms (convection, diffusion and migration) is presented. In addition, non‐linear phenomenological electrode kinetics boundary conditions are accounted for. The governing equations form a set of coupled non‐linear partial differential equations subject to an algebraic constraint due to the electroneutrality condition. The advantage of a convective formulation of the ion‐transport equations with respect to a natural application of homogeneous flux boundary conditions is emphasized. For one of the numerical examples, an analytical solution for the coupled problem is provided, and it is demonstrated that the proposed computational approach is robust and provides accurate results. Copyright © 2011 John Wiley & Sons, Ltd.