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Estimation of Apparent Kinetic Constants of Individual Site Types for the Polymerization of Ethylene and α‐olefins with Ziegler–Natta Catalysts
Author(s) -
Chen Keran,
Mehdiabadi Saeid,
Liu Boping,
Soares João B. P.
Publication year - 2016
Publication title -
macromolecular reaction engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.37
H-Index - 32
eISSN - 1862-8338
pISSN - 1862-832X
DOI - 10.1002/mren.201600003
Subject(s) - natta , polymerization , ziegler–natta catalyst , polymer , catalysis , ethylene , polymer chemistry , kinetics , molar mass distribution , olefin polymerization , materials science , chemistry , organic chemistry , physics , quantum mechanics
This article proposes a method to quantify the polymerization kinetics of ethylene and α‐olefins with commercial TiCl 4 /MgCl 2 Ziegler–Natta catalysts. The method determines the leading apparent polymerization kinetic constants for each active site in a Ziegler–Natta catalyst by simultaneously fitting the instantaneous polymerization rate, cumulative polymer yield, and polymer molecular weight distribution measured at different times during a series of semi‐batch polymerization experiments. This approach quantifies the behavior of olefin polymerization with multisite catalysts using the least number of adjustable parameters needed to consistently model polymerization kinetics and polymer microstructural data.