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A Kinetic Model for Non‐Oxidative Thermal Degradation of Nylon 66
Author(s) -
Karimi Hadiseh,
Schaffer Mark A.,
McAuley Kim B.
Publication year - 2012
Publication title -
macromolecular reaction engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.37
H-Index - 32
eISSN - 1862-8338
pISSN - 1862-832X
DOI - 10.1002/mren.201100051
Subject(s) - cyclopentanone , degradation (telecommunications) , thermodynamics , thermal , mathematics , kinetic energy , amine gas treating , chemistry , phase (matter) , materials science , polymer chemistry , organic chemistry , physics , computer science , telecommunications , quantum mechanics , catalysis
A model is developed to predict rates of undesirable reactions in the low‐moisture, high‐temperature finishing stage of nylon 66 production. The model contains 56 unknown parameters and initial conditions, which are ranked based on their influence on model predictions, correlation with other parameters and uncertainty in their initial guesses. A mean‐square‐error criterion is used to determine that 43 of 56 parameters should be estimated. The proposed model, which describes the effect of melt‐phase water concentration on degradation, matches the data well with typical errors of 6.1 and 2.9%, respectively, for amine ends (A) and carboxyl ends (C) and 4.3, 27.2, and 29.4%, respectively, for evolution rates of CO 2 , NH 3 , and cyclopentanone (CPK).