Assignment of the  13 C and  15 N NMR spectra of the antitumour antibiotic streptonigrin | Zendy

Anderberg Pia I. | Zendy; Luck Ian J. | Zendy; Harding Margaret M. | Zendy

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Assignment of the 13 C and 15 N NMR spectra of the antitumour antibiotic streptonigrin

Author(s) -

Anderberg Pia I.,

Luck Ian J.,

Harding Margaret M.

Publication year - 2002

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.997

Subject(s) - chemistry , heteronuclear single quantum coherence spectroscopy , dept , carbon 13 nmr , stereochemistry , nmr spectra database , spectral line , nuclear magnetic resonance spectroscopy , physics , astronomy

The assignments of the two pyridyl nitrogens and two amino nitrogens in the antitumour antibiotic streptonigrin, and all carbon resonances, were determined by 15 N (HSQC, HMBC) and 13 C (HSQC, HMBC) NMR techniques. These data provide useful probes for determination of the site(s) of metal complexation in the drug, which are important in the mechanism of antitumour activity. Copyright © 2002 John Wiley & Sons, Ltd.

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