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Unequivocal assignment of the fullerene carbons of diethyl 1,2‐methano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy
Author(s) -
Burley Glenn A.,
Keller Paul A.,
Pyne Stephen G.,
Ball Graham E.
Publication year - 2001
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.879
Subject(s) - fullerene , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , carbon 13 nmr , folding (dsp implementation) , resolution (logic) , phase (matter) , crystallography , analytical chemistry (journal) , topology (electrical circuits) , computational chemistry , stereochemistry , organic chemistry , combinatorics , physics , mathematics , quantum mechanics , artificial intelligence , computer science , electrical engineering , engineering
Assignment of all carbons of the [60]fullerene sphere of diethyl 1,2‐methnano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy is described. Acquiring the INADEQUATE data with small spectral widths and optional F 1 folding with States‐TPPI phase implementation provides a convenient route to high‐resolution data. A description of the topology of the [60]fullerene sphere and its comparison with x‐ray crystallographic analysis is also presented. Copyright © 2001 John Wiley & Sons, Ltd.