Unequivocal assignment of the fullerene carbons of diethyl 1,2‐methano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy | Zendy

Burley Glenn A. | Zendy; Keller Paul A. | Zendy; Pyne Stephen G. | Zendy; Ball Graham E. | Zendy

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Unequivocal assignment of the fullerene carbons of diethyl 1,2‐methano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy

Author(s) -

Burley Glenn A.,

Keller Paul A.,

Pyne Stephen G.,

Ball Graham E.

Publication year - 2001

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.879

Subject(s) - fullerene , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , carbon 13 nmr , folding (dsp implementation) , resolution (logic) , phase (matter) , crystallography , analytical chemistry (journal) , topology (electrical circuits) , computational chemistry , stereochemistry , organic chemistry , combinatorics , physics , mathematics , quantum mechanics , artificial intelligence , computer science , electrical engineering , engineering

Assignment of all carbons of the [60]fullerene sphere of diethyl 1,2‐methnano[60]fullerene 61,61‐dicarboxylate using 2D INADEQUATE NMR spectroscopy is described. Acquiring the INADEQUATE data with small spectral widths and optional F 1 folding with States‐TPPI phase implementation provides a convenient route to high‐resolution data. A description of the topology of the [60]fullerene sphere and its comparison with x‐ray crystallographic analysis is also presented. Copyright © 2001 John Wiley & Sons, Ltd.

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