Premium
Self‐reactivity of s‐triazine and its radical cation: an electron/proton transfer process driven by ionizing radiation
Author(s) -
Rhodes Christopher J.,
Moynihan Humphrey A.
Publication year - 2001
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.811
Subject(s) - chemistry , deprotonation , radical , triazine , reactivity (psychology) , photochemistry , ionizing radiation , proton , solvent , molecule , radical ion , ion , polymer chemistry , organic chemistry , irradiation , medicine , physics , alternative medicine , pathology , quantum mechanics , nuclear physics
Exposure of solutions of s‐triazine in a trichlorofluoromethane matrix at 77 K to γ‐radiation resulted in the formation of s‐triazinyl radicals by deprotonation of the primary radical cations. The results indicate that neutral s‐triazine molecules dissolve in an associated state in the Freon solvent. Copyright © 2001 John Wiley & Sons, Ltd.