Synthesis of a new 1,2,3,4,5‐pentasubstituted cyclohexanol and determining its stereochemistry by NMR spectroscopy and quantum‐chemical calculations | Zendy

Mamedov Ibrahim | Zendy; Abbasoglu Rza | Zendy; Bayramov Musa | Zendy; Maharramov Abel | Zendy

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Synthesis of a new 1,2,3,4,5‐pentasubstituted cyclohexanol and determining its stereochemistry by NMR spectroscopy and quantum‐chemical calculations

Author(s) -

Mamedov Ibrahim,

Abbasoglu Rza,

Bayramov Musa,

Maharramov Abel

Publication year - 2016

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.4377

Subject(s) - chemistry , cyclohexanol , conformational isomerism , cyclohexane , quantum chemical , nuclear magnetic resonance spectroscopy , computational chemistry , stereochemistry , chemical shift , spectroscopy , derivative (finance) , organic chemistry , molecule , catalysis , physics , quantum mechanics , financial economics , economics

The presence of substituents in cyclohexane can influence to the ratio of conformers; for some cases, the boat form is preferable. The new six‐membered cyclohexanol derivative 2 has been obtained by the synthesis of ( E )‐1‐(bromophenyl)‐3‐phenylpropen‐2‐one ( 1 ). The NMR and quantum‐chemical conformational analysis for the 2 have carried out, and its possible mechanism of formation was given. Copyright © 2015 John Wiley & Sons, Ltd.

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