NMR  study of localization and mobility of 1‐phenylethanol enantiomers in homochiral metal‐organic sorbent  Zn 2  (bdc)(  S  ‐lac)(dmf) | Zendy

Gallyamov M. R. | Zendy; Yutkin M. P. | Zendy; Moroz N. K. | Zendy; Kozlova S. G. | Zendy; Gabuda S. P. | Zendy

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NMR study of localization and mobility of 1‐phenylethanol enantiomers in homochiral metal‐organic sorbent Zn 2 (bdc)( S ‐lac)(dmf)

Author(s) -

Gallyamov M. R.,

Yutkin M. P.,

Moroz N. K.,

Kozlova S. G.,

Gabuda S. P.

Publication year - 2015

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.4262

Subject(s) - chemistry , enantiomer , sorbent , nuclear magnetic resonance spectroscopy , metal , stereochemistry , organic chemistry , adsorption

Structural features of localization of chiral isomers of 1‐phenylethanol ( R ‐PhEtOH and S ‐PhEtOH) and their mobility activation in homochiral metal‐organic [Zn 2 (bdc)( S ‐lac)(dmf)] sorbent were studied with 1 H and 13 C NMR methods. 13 C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S ‐PhEtOH and R ‐PhEtOH clearly indicates that stabilization of [Zn 2 (bdc)( S ‐lac)(dmf)]· S ‐PhEtOH structure is more preferable than stabilization of [Zn 2 (bdc)( S ‐lac)(dmf)]· R ‐PhEtOH structure. Copyright © 2015 John Wiley & Sons, Ltd.

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