Conformational equilibrium and dynamic behavior of  bis‐N ‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane | Zendy

Shainyan Bagrat A. | Zendy; Moskalik Mikhail Yu. | Zendy; Heydenreich Matthias | Zendy; Kleinpeter Erich | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Conformational equilibrium and dynamic behavior of bis‐N ‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane

Author(s) -

Shainyan Bagrat A.,

Moskalik Mikhail Yu.,

Heydenreich Matthias,

Kleinpeter Erich

Publication year - 2014

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.4086

Subject(s) - chemistry , conformational isomerism , octane , computational chemistry , derivative (finance) , nuclear magnetic resonance spectroscopy , spectroscopy , internal rotation , crystallography , stereochemistry , organic chemistry , molecule , mechanical engineering , physics , quantum mechanics , financial economics , engineering , economics

Restricted rotation about the N–S partial double bonds in a bis‐N ‐triflyl substituted 3,8‐diazabicyclo[3.2.1]octane derivative 1 has been frozen at low temperature ( Δ G ≠ = 11.6 kcal mol −1 ), and the existence of all four rotamers about the two N–S bonds, 3‐in,8‐in , 3‐in,8‐out , 3‐out,8‐in , and 3‐ out,8‐out , respectively, proved experimentally by NMR spectroscopy and theoretically by DFT and MP2 calculations. Copyright © 2014 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research