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Preparation of adamantyl derivatives of 1,4‐; 1,6‐ and 1,7‐dihydroxynaphthalenes and assignment of their NMR data
Author(s) -
Peterson Ivan V.,
Svirskaya Nadezhda M.,
Kondrasenko Alexander A.,
Rubaylo Anatoliy I.
Publication year - 2013
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.4010
Subject(s) - chemistry , adamantane , stereochemistry , proton nmr , carbon 13 nmr , combinatorial chemistry , organic chemistry
Adamantylation of dihydroxynaphthalenes with the hydroxyl groups on the same or different rings leads to compounds that are convenient starting materials in target‐oriented organic synthesis. Here, we report the 1 H and 13 C NMR assignments of eight 1‐adamantyl substituted derivatives of 1,4‐; 1,6‐ and 1,7‐dihydroxynaphthalenes. The data acquired and peculiarities of their molecular structure are useful for extrapolation for prompt characterization of compounds containing adamantane, dihydroxynaphthalenes or naphthoquinone units. Copyright © 2013 John Wiley & Sons, Ltd.