Full assignment of the  1 H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long‐range interligand NOEs | Zendy

Mugeniwabagara Epiphanie | Zendy; Fusaro Luca | Zendy; Luhmer Michel | Zendy

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Full assignment of the 1 H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long‐range interligand NOEs

Author(s) -

Mugeniwabagara Epiphanie,

Fusaro Luca,

Luhmer Michel

Publication year - 2013

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.3931

Subject(s) - chemistry , ruthenium , octahedron , nuclear magnetic resonance spectroscopy , crystallography , metal , spectrum (functional analysis) , range (aeronautics) , chemical shift , stereochemistry , organic chemistry , crystal structure , physics , quantum mechanics , catalysis , materials science , composite material

Chemical equivalence in symmetrical polyazaaromatic ligands is not necessarily retained in the corresponding heteroleptic ruthenium(II) complexes, and the assignment of the 1 H NMR spectrum of these octahedral metallic compounds is therefore not straightforward. This work shows that full assignment can be achieved on the basis of long‐range interligand NOE measurements. Copyright © 2013 John Wiley & Sons, Ltd.

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