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A simple method for the determination of the partitioning of nitroxide probes in microheterogeneous media
Author(s) -
Aliaga Carolina,
Torres Paulina,
Silva Fernanda
Publication year - 2012
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.3871
Subject(s) - chemistry , simple (philosophy) , nitroxide mediated radical polymerization , chromatography , analytical chemistry (journal) , computational chemistry , organic chemistry , polymer , philosophy , radical polymerization , epistemology , copolymer
The use of the ESR g ‐factor of spin labels for the easy and clean assessment of their partitioning in microheterogeneous media is described. The method constitutes a valuable alternative in those cases where the classical Benesi–Hildebrand treatment, based on UV–visible measurements, is difficult or not feasible. Copyright © 2012 John Wiley & Sons, Ltd.