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Differentiation and assignment of vinyl telluride regioisomers by 1 H‐ 125 Te g HMBC
Author(s) -
Freitas Juliano C. R.,
Palmeira Dayvson J.,
Oliveira Roberta A.,
Menezes Paulo H.,
Silva Ricardo O.
Publication year - 2012
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.3826
Subject(s) - structural isomer , chemistry , carbon 13 nmr , stereochemistry , telluride , organic chemistry
Complete 1 H, 13 C, and 125 Te NMR spectral data for some vinyl tellurides are described. The 1 H– 125 Te g HMBC experiment was used for the complete chemical shift assignment and structure elucidation of a mixture of regioisomers. The assignment ( 125 Te NMR) and coupling constants ( J H,H ) for all regioisomers are described for the first time. Copyright © 2012 John Wiley & Sons, Ltd.