Premium
Nuclear magnetic resonance spectroscopic analysis of ethyl ester yield in the transesterification of vegetable oil: an accurate method for a truly quantitative analysis
Author(s) -
Mambrini Giovanni Pimenta,
Ribeiro Caue,
Colnago Luiz Alberto
Publication year - 2012
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.2831
Subject(s) - biodiesel , transesterification , chemistry , yield (engineering) , nuclear magnetic resonance spectroscopy , diesel fuel , analytical chemistry (journal) , biodiesel production , proton nmr , relaxation (psychology) , nuclear magnetic resonance , organic chemistry , thermodynamics , catalysis , physics , psychology , social psychology
Biodiesel has recently gained importance as an alternative to fossil diesel. However, the development of more efficient biodiesel formation processes still depends on the use of fast and accurate analytical techniques to evaluate the conversion degree of the transesterification reaction. Nuclear magnetic resonance (NMR) spectroscopy has been used for this purpose, but some experimental details still need to be addressed. Therefore, in this communication, the experimental conditions for a truly quantitative NMR analysis of biodiesel formation are presented. The longitudinal relaxation time ( T 1 ), which is the determining factor for quantitative analysis, was measured using an inversion‐recovery method, and a maximum value of 2.35 s was obtained for a biodiesel sample. A linear determination coefficient of r 2 = 0.99 was obtained when a time delay between pulses longer than 5 T 1 =15 s was used, whereas strong deviations were observed when using shorter delays. Copyright © 2012 John Wiley & Sons, Ltd.