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1 H and 13 C NMR spectral data of bioactive cage‐like polycyclic compounds
Author(s) -
Salles Roberta C.,
Lacerda Valdemar,
Beatriz Adilson,
Ito Felicia M.,
dos Santos Reginaldo B.,
Greco, Sandro J.,
de Castro Eustáquio V. R.,
de Lima Dênis P.
Publication year - 2010
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.2588
Subject(s) - chemistry , cage , carbon 13 nmr , nuclear magnetic resonance spectroscopy , stereochemistry , combinatorics , mathematics
Bioactive cage‐like polycyclic compounds have attracted the attention of several research groups because of their unique appearance and their biological activities. Their structures were established on the basis of 1 H NMR and 13 C NMR spectroscopic data. The 1 H and 13 C signal assignments and most homonuclear hydrogen coupling constants were assigned by use of techniques such as 1D 1 H and 13 C NMR and 2D gCOSY, non‐edited gHSQC and gHMBC. The gNOESY experiments proved the endo‐stereochemistry. Copyright © 2010 John Wiley & Sons, Ltd.
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