Experimental and quantum‐chemical studies of  1 H,  13 C and  15 N NMR coordination shifts in Au(III), Pd(II) and Pt(II) chloride complexes with picolines | Zendy

Pazderski Leszek | Zendy; Toušek Jaromír | Zendy; Sitkowski Jerzy | Zendy; Maliňáková Kateřina | Zendy; Kozerski Lech | Zendy; Szłyk Edward | Zendy

Premium

Experimental and quantum‐chemical studies of 1 H, 13 C and 15 N NMR coordination shifts in Au(III), Pd(II) and Pt(II) chloride complexes with picolines

Author(s) -

Pazderski Leszek,

Toušek Jaromír,

Sitkowski Jerzy,

Maliňáková Kateřina,

Kozerski Lech,

Szłyk Edward

Publication year - 2009

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.2378

Subject(s) - chemistry , chemical shift , platinum , palladium , chloride , nuclear magnetic resonance spectroscopy , stereochemistry , medicinal chemistry , catalysis , organic chemistry

1 H, 13 C and 15 N NMR studies of gold(III), palladium(II) and platinum(II) chloride complexes with picolines, [Au(PIC)Cl 3 ], trans ‐[Pd(PIC) 2 Cl 2 ], trans / cis ‐[Pt(PIC) 2 Cl 2 ] and [Pt(PIC) 4 ]Cl 2 , were performed. After complexation, the 1 H and 13 C signals were shifted to higher frequency, whereas the 15 N ones to lower (by ca 80–110 ppm), with respect to the free ligands. The 15 N shielding phenomenon was enhanced in the series [Au(PIC)Cl 3 ] < trans ‐[Pd(PIC) 2 Cl 2 ] < cis ‐[Pt(PIC) 2 Cl 2 ] < trans ‐[Pt(PIC) 2 Cl 2 ]; it increased following the Pd(II) → Pt(II) replacement, but decreased upon the trans → cis ‐transition. Experimental 1 H, 13 C and 15 N NMR chemical shifts were compared to those quantum‐chemically calculated by B3LYP/LanL2DZ + 6‐31G**//B3LYP/LanL2DZ + 6‐31G*. Copyright © 2008 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research