Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through  para ‐hydrogen‐enhanced NMR methods | Zendy

Godard Cyril | Zendy; LópezSerrano Joaquín | Zendy; GálvezLópez MaríaDolores | Zendy; RosellóMerino Marta | Zendy; Duckett Simon B. | Zendy; Khazal Iman | Zendy; Lledós Agustí | Zendy; Whitwood Adrian C. | Zendy

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Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para ‐hydrogen‐enhanced NMR methods

Author(s) -

Godard Cyril,

LópezSerrano Joaquín,

GálvezLópez MaríaDolores,

RosellóMerino Marta,

Duckett Simon B.,

Khazal Iman,

Lledós Agustí,

Whitwood Adrian C.

Publication year - 2008

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.2342

Subject(s) - chemistry , reactivity (psychology) , platinum , hydride , hydrogen , proton nmr , medicinal chemistry , stereochemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology

In‐situ NMR studies on the reactions of Pt{CH 2 = CHSi(Me) 2 } 2 O)(PCy 3 ) with phosphines, HSiEt 3 and ‐ hydrogen or Pt(L)(L′)(Me) 2 alone enable the detection of cis ‐Pt(L)(L′)(H) 2 [L = PCy 3 and L′ = PCy 2 H, PPh 3 or PCy 3 ] which then undergo hydride site interchange and H 2 reductive elimination on the NMR timescale. Copyright © 2008 John Wiley & Sons, Ltd.

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