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Substituent effects of the N , N ‐dimethyl‐ sulfamoyl group on the 1 H and 13 C NMR spectra of positional isomers of quinolines
Author(s) -
Maślankiewicz Andrzej,
Maślankiewicz Maria J.,
Marciniec Krzysztof
Publication year - 2008
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.2150
Subject(s) - chemistry , substituent , quinoline , chemical shift , benzene , pyridine , ring (chemistry) , carbon 13 nmr , stereochemistry , proton , structural isomer , nmr spectra database , nuclear magnetic resonance spectroscopy , proton nmr , spectral line , medicinal chemistry , crystallography , organic chemistry , physics , quantum mechanics , astronomy
The complete 1 H and 13 C NMR spectral assignments of seven positional isomers of N , N ‐dimethylsulfamoylquinolines 2–8 and quinoline have been made using 1D and 2D NMR techniques, including COSY, HMQC and HMBC experiments. Δδ H and Δδ C substituent effects induced by the sulfamoyl group were determined. The sulfamoyl substituent affects proton and carbon chemical shifts both in the parent and in the fused (pyridine or benzene) ring. Copyright © 2007 John Wiley & Sons, Ltd.

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