Premium
17 O NMR investigation of phosphite hydrolysis mechanisms
Author(s) -
McIntyre Sarah K.,
Alam Todd M.
Publication year - 2007
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.2094
Subject(s) - chemistry , hydrolysis , nuclear magnetic resonance spectroscopy , nmr spectra database , trimethyl phosphite , phosphorus 31 nmr spectroscopy , fluorine 19 nmr , proton nmr , kinetic energy , reaction mechanism , carbon 13 nmr , organic chemistry , spectral line , catalysis , physics , quantum mechanics , astronomy
The use of solution 17 O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17 O‐labeled H 2 O at different temperatures and two reactant concentrations, with the reaction being monitored by 17 O NMR. Kinetic details elucidated from the NMR spectra are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.