17 O NMR investigation of phosphite hydrolysis mechanisms | Zendy

McIntyre Sarah K. | Zendy; Alam Todd M. | Zendy

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17 O NMR investigation of phosphite hydrolysis mechanisms

Author(s) -

McIntyre Sarah K.,

Alam Todd M.

Publication year - 2007

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.2094

Subject(s) - chemistry , hydrolysis , nuclear magnetic resonance spectroscopy , nmr spectra database , trimethyl phosphite , phosphorus 31 nmr spectroscopy , fluorine 19 nmr , proton nmr , kinetic energy , reaction mechanism , carbon 13 nmr , organic chemistry , spectral line , catalysis , physics , quantum mechanics , astronomy

The use of solution 17 O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17 O‐labeled H 2 O at different temperatures and two reactant concentrations, with the reaction being monitored by 17 O NMR. Kinetic details elucidated from the NMR spectra are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.

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