Configurational assignment of  N ‐arylsulfonylimines of α‐polychloroaldehydes | Zendy

Krivdin Leonid B. | Zendy; Chernyshev Kirill A. | Zendy; Rosentsveig Gulnur N. | Zendy; Ushakova Irina V. | Zendy; Rosentsveig Igor B. | Zendy; Levkovskaya Galina G. | Zendy

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Configurational assignment of N ‐arylsulfonylimines of α‐polychloroaldehydes

Author(s) -

Krivdin Leonid B.,

Chernyshev Kirill A.,

Rosentsveig Gulnur N.,

Ushakova Irina V.,

Rosentsveig Igor B.,

Levkovskaya Galina G.

Publication year - 2007

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.2070

Subject(s) - chemistry , ab initio , coupling constant , computational chemistry , spin (aerodynamics) , line (geometry) , ab initio quantum chemistry methods , thermodynamics , molecule , organic chemistry , quantum mechanics , physics , geometry , mathematics

Configurational assignment of seven synthesized N ‐arylsulfonylimines of α‐polychloroaldehydes has been carried out by means of experimental measurements and high‐level ab initio calculations of their 13 C 13 C, 13 C 1 H and 15 N 1 H spin–spin coupling constants. The title compounds were shown to exist in solution solely in the form of E isomers, in line with thermodynamic reasoning. Copyright © 2007 John Wiley & Sons, Ltd.

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