2  J ( 29 SiO 29 Si) coupling constants in oligosiloxanes | Zendy

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2 J ( 29 SiO 29 Si) coupling constants in oligosiloxanes

Author(s) -

Kurfürst Milan,

Schraml Jan

Publication year - 2007

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.2021

Subject(s) - chemistry , coupling constant , moiety , spin (aerodynamics) , branching (polymer chemistry) , range (aeronautics) , coupling (piping) , analytical chemistry (journal) , atomic physics , computational chemistry , stereochemistry , organic chemistry , thermodynamics , quantum mechanics , physics , mechanical engineering , materials science , engineering , composite material

The absolute values of spin–spin couplings between 29 Si nuclei in siloxanes, 2 J ( 29 SiO 29 Si), were determined. The couplings are small and cover a narrow range of values (0–5 Hz). The coupling constants depend on the branching or on the number of electronegative substituents on the SiOSi moiety. Copyright © 2007 John Wiley & Sons, Ltd.

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