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NMR spectral assignments of a new chlorotryptamine alkaloid and its analogues from Acacia confusa
Author(s) -
Buchanan Malcolm S.,
Carroll Anthony R.,
Pass David,
Quinn Ronald J.
Publication year - 2007
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1959
Subject(s) - chemistry , alkaloid , dept , stereochemistry , two dimensional nuclear magnetic resonance spectroscopy , carbon 13 nmr , methanol , organic chemistry
A new chlorotryptamine alkaloid, N ‐chloromethyl‐ N , N ‐dimethyltryptamine, was isolated from a methanol extract of the Chinese shrub Acacia confusa Merr., together with its known hallucinogenic analogues, N ‐methyltryptamine, N , N ‐dimethyltryptamine and N , N ‐dimethyltryptamine‐ N ‐oxide. The new compound was an artefact of the isolation conditions. The complete 1 H and 13 C NMR assignments for these compounds were carried out using 1 H, 13 C, DEPT, gCOSY, gHSQC and gHMBC NMR experiments. Copyright © 2007 John Wiley & Sons, Ltd.
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