‘Magic blue’ — subtle reagent for EPR studies on H‐abstraction from various substrates | Zendy

Dou HongYan | Zendy; Ni HongBo | Zendy; Lin ZhengHuan | Zendy; Zhao ChengXue | Zendy

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‘Magic blue’ — subtle reagent for EPR studies on H‐abstraction from various substrates

Author(s) -

Dou HongYan,

Ni HongBo,

Lin ZhengHuan,

Zhao ChengXue

Publication year - 2006

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1769

Subject(s) - chemistry , reagent , alkoxy group , electron paramagnetic resonance , nitroxide mediated radical polymerization , magic (telescope) , medicinal chemistry , organic chemistry , polymer , alkyl , nuclear magnetic resonance , physics , radical polymerization , copolymer , quantum mechanics

This paper is an EPR study on the generation of new ‘magic blue’ (MB) reagent containing bis{perfluoro[1‐(2‐fluorosulfonyl)ethoxy]ethyl}nitroxide 2 and perfluoro[1‐nitroso‐1‐(2‐fluorosulfonyl)ethoxy]ethane 3, both bearing chemically convertible terminal ω‐fluorosulfonyl group SO 2 F, and its H‐abstraction reactions from arylalkanes, alcohols, aldehydes and polymers, leading to a large number of new fluorinated nitroxides (FN). Copyright © 2006 John Wiley & Sons, Ltd.

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